This particular issue will occur if the rubber seat on the radiator cap has shrunk or warped. Have fixed my car as well as my mates with simply replacing the rad cap. Have you checked below the car as well to see if there's any fluid? Or inside the cabin area underneath the carpet? If not, check it as the heater core might also be leaking.

I racked my brains trying to fix this issue of mine...replaced all the piping in the car, till one day my window fogged up inside the cabin. I only managed to fix this when I tore the car down for a build project since I couldn't be f'd taking the dash out of a working car.